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Samarium(II) iodide mediated transformations of carbohydrate derived alkenyl iodides

✍ Scribed by Zhihong Zhou; Sharon M. Bennett

Book ID
104256385
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
221 KB
Volume
38
Category
Article
ISSN
0040-4039

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Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined alkoxy aminocyclopentanes. This rapid samarium diiodide promoted conversion involves intramolecular trapping of a radical by an oxime ether.

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## Samarium(II) Iodide Mediated Transformations of Carbohydrate Derived Iodo Oxime Ethers into Stereodefined Alkoxy Aminocyclopentanes. -The samarium diiodide promoted cyclization of carbohydrate derived iodo oxime ethers (I) and (IV) into stereodefined aminocyclopentanes (II)/(III) and (V) invol