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Samarium(II) iodide mediated transformation of carbohydrates to carbocycles

✍ Scribed by Enholm, Eric J.; Trivellas, Antigone

Book ID
120971827
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
420 KB
Volume
111
Category
Article
ISSN
0002-7863

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Samarium (II) iodide mediated transforma
Samarium (II) iodide mediated transformations of carbohydrate derived iodo oxime ethers into stereodefined alkoxy aminocyclopentanes
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Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined alkoxy aminocyclopentanes. This rapid samarium diiodide promoted conversion involves intramolecular trapping of a radical by an oxime ether.

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## Samarium(II) Iodide Mediated Transformations of Carbohydrate Derived Iodo Oxime Ethers into Stereodefined Alkoxy Aminocyclopentanes. -The samarium diiodide promoted cyclization of carbohydrate derived iodo oxime ethers (I) and (IV) into stereodefined aminocyclopentanes (II)/(III) and (V) invol