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Samarium (II) iodide mediated transformations of carbohydrate derived iodo oxime ethers into stereodefined alkoxy aminocyclopentanes

✍ Scribed by J.J. Cronjé; Cedric W. Holzapfel

Book ID
104258051
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
167 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined alkoxy aminocyclopentanes. This rapid samarium diiodide promoted conversion involves intramolecular trapping of a radical by an oxime ether.

📜 SIMILAR VOLUMES

ChemInform Abstract: Samarium(II) Iodide
ChemInform Abstract: Samarium(II) Iodide Mediated Transformations of Carbohydrate Derived Iodo Oxime Ethers into Stereodefined Alkoxy Aminocyclopentanes.
✍ J. J. C. GROVE; C. W. HOLZAPFEL 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

## Samarium(II) Iodide Mediated Transformations of Carbohydrate Derived Iodo Oxime Ethers into Stereodefined Alkoxy Aminocyclopentanes. -The samarium diiodide promoted cyclization of carbohydrate derived iodo oxime ethers (I) and (IV) into stereodefined aminocyclopentanes (II)/(III) and (V) invol