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ChemInform Abstract: Samarium(II) Iodide Mediated Transformations of Carbohydrate Derived Iodo Oxime Ethers into Stereodefined Alkoxy Aminocyclopentanes.

✍ Scribed by J. J. C. GROVE; C. W. HOLZAPFEL

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Samarium(II) Iodide Mediated Transformations of Carbohydrate

Derived Iodo Oxime Ethers into Stereodefined Alkoxy Aminocyclopentanes.

-The samarium diiodide promoted cyclization of carbohydrate derived iodo oxime ethers (I) and (IV) into stereodefined aminocyclopentanes (II)/(III) and (V) involves an intramolecular trapping of a radical by the oxime ether. -(GROVE,

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