## Abstract Terminal acetylenes react with __cis__‐RuMe~2~(PMe~3~)~4~ to form the bis(acetylido) complexes __cis__/__trans__‐Ru(C≡CR)~2~(PMe~3~)~4~ in good yield. The structures of __trans__‐2 (R = Ph), __cis__‐3 (R = __p__‐C~6~H~4~‐OMe), __trans__‐4 (R = __p__‐C~6~H~4~‐Me), __cis__‐6 (R = Me), __t
Ruthenium(II) Complexes Bearing Carboxylato and 2-Oxocarboxylato Ligands
✍ Scribed by Rainer Müller; Eike Hübner; Nicolai Burzlaff
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 216 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
Chelate ligands containing at least one pyrazole group were treated with RuCl 2 (PPh 3 ) 3 , RuHCl(CO)(PPh 3 ) 3 and RuH 2 (CO)-(PPh 3 ) 3 to form ruthenium complexes bearing protic N-H groups in close proximity to the catalytically active ruthenium centre. In the case of the hydridoruthenium comple
## Abstract The new tridentate ligand 4‐(3,4‐methylenedioxyphenyl)‐2,6‐dipyrazinylpyridine (2) was prepared in good yield in a one‐pot reaction. The Ru^II^ complexes [Ru(2)~2~](PF~6~)~2~ and [Ru(1)(2)](PF~6~)~2~ [1 is 2,6‐dipyrazinyl‐4‐(4‐tolyl)pyridine] were prepared in good yields and tested as p