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Ruthenium Complexes Bearing N–H Acidic Pyrazole Ligands

✍ Scribed by Thomas Jozak; Dirk Zabel; Anett Schubert; Yu Sun; Werner R. Thiel

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
975 KB
Volume
2010
Category
Article
ISSN
1434-1948

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✦ Synopsis

Chelate ligands containing at least one pyrazole group were treated with RuCl 2 (PPh 3 ) 3 , RuHCl(CO)(PPh 3 ) 3 and RuH 2 (CO)-(PPh 3 ) 3 to form ruthenium complexes bearing protic N-H groups in close proximity to the catalytically active ruthenium centre. In the case of the hydridoruthenium complex RuHCl(CO)(PPh 3 ) 3 the resulting complexes also contain a [

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