Magnesium Complexes Bearing η2-Pyrazolato Ligands
✍ Scribed by Dirk Pfeiffer; Mary Jane Heeg; Charles H. Winter
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 108 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reduction of [L 2 TiCl 2 ] (1) (L = 3,5-tert-butylpyrazolate) is isolated as light blue crystals in low yield. An alternative procedure for preparing compound 4 requires mixing with 1% Na/Hg in tetrahydrofuran (THF) affords the complex [L 2 TiCl(THF) 2 ] (2), which crystallizes from hexane [TiCl
1,3.5-Tris[diazo(3-(diazo(3-(diazo(phenyl)methyl)phenyl)methyl)phenyl)methyllbenzene (4d): The nonaketone 4 b was converted to the corresponding nonahydrazone 4 c by the addition of anhydrous hydrazine and hydrazine hydrochloride in dimethyl sulfoxide (DMSO) at 90'C. The nonahydrazone 4c was then o