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Synthesis, Structure, and Properties of Zirconium and Hafnium Complexes Containing η2-Pyrazolato Ligands

✍ Scribed by Elena Sebe; Ilia A. Guzei; Mary Jane Heeg; Louise M. Liable-Sands; Arnold L. Rheingold; Charles H. Winter


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
154 KB
Volume
2005
Category
Article
ISSN
1434-1948

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✍ Norbert Stock; Wolfgang Herrendorf; Johannes Beck; Wolfgang Schnick 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 673 KB

## The (trimetaphosphimato)hafnates and -zirconates Na 4 {Hf 4 (µ 4 -O)(µ-OH) 6 [(PO 2 NH) ), c = 50.284(10) A ˚, Z = 6] were obtained by the stoichiometric reaction of HfOCl 2 • 8 H 2 O and ZrOCl 2 • 8 H 2 O with an aqueous solution of Na 3 (PO 2 NH) 3 • 4 H 2 O, followed by the diffusion-control