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RuCl2(PPh3)3 - Catalyzed transfer hydrogenation of cyclohexane - 1,3 - diones

✍ Scribed by Y. Sasson; J. Blum; E. Dunkelblum


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
171 KB
Volume
14
Category
Article
ISSN
0040-4039

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N,Nβ€²-Dialkylated 1,2-diamine derivatives
✍ Geon-Joong Kim; Sang-Han Kim; Pong-Hyun Chong; Mi-Ae Kwon πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 110 KB

Chiral N,N%-dialkylated cyclohexanediamine derivatives ligands have been synthesized and used in an asymmetric transfer hydrogenation of aryl ketones. Optically active alcohols with up to 93% enantiomeric excess were obtained in high yield.