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ChemInform Abstract: RuCl2(PPh3)3 Catalyzed Isomerization of the Baylis—Hillman Adducts.

✍ Scribed by Deevi Basavaiah; Kannan Muthukumaran

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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## Abstract A new and convenient stereoselective synthesis of (__Z__)‐2‐(chloromethyl)alk‐2‐enoates has been achieved from __Baylis–Hillman__ adducts by treatment with PPh~3~/Cl~3~CCONH~2~ at room temperature. The synthesis can proceed under mild and acid‐free conditions to form the products in hig