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RuCl2(PPh3)3-catalyzed transfer hydrogenation of d-glucose

โœ Scribed by S. Rajagopal; S. Vancheesan; J. Rajaram; J.C. Kuriacose

Publisher
Elsevier Science
Year
1992
Weight
688 KB
Volume
75
Category
Article
ISSN
0304-5102

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Chiral N,N%-dialkylated cyclohexanediamine derivatives ligands have been synthesized and used in an asymmetric transfer hydrogenation of aryl ketones. Optically active alcohols with up to 93% enantiomeric excess were obtained in high yield.