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N,N′-Dialkylated 1,2-diamine derivatives as new efficient ligands for RuCl2(PPh3)3 catalyzed asymmetric transfer hydrogenation of aromatic ketones

✍ Scribed by Geon-Joong Kim; Sang-Han Kim; Pong-Hyun Chong; Mi-Ae Kwon

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
110 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

Chiral N,N%-dialkylated cyclohexanediamine derivatives ligands have been synthesized and used in an asymmetric transfer hydrogenation of aryl ketones. Optically active alcohols with up to 93% enantiomeric excess were obtained in high yield.

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