𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rotating sector study of the gas phase photolysis of the 1,1,1-trichloro-2,2,2-trifluoroethane–cyclohexane system

✍ Scribed by Fred B. Wampler; Robert R. Kuntz

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
348 KB
Volume
3
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The rate constant for the combination of 1,1‐dichloro‐2,2,2‐trifluoroethyl radicals in the gas phase has been measured by applying the rotating sector technique to the 1,1,1‐trichloro‐2,2,2‐trifluoroethane–cyclohexane photochemical system. The combination rate constant, k~5~, was found to be 6.6 × 10^12^ cc mole^−1^ sec^−1^. Arrhenius parameters for the reaction, magnified image are given by the expression log k~4~ = 11.81 – (9700/2.3__RT__).

📜 SIMILAR VOLUMES

Rotating sector study of the gas phase p
Rotating sector study of the gas phase photochlorination of 2,2-dichloro-1,1,1-trifluoroethane
✍ R. F. Cullison; R. C. Pogue; M. L. White 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 413 KB

The rate constant for the combination of 2,2-dichloro-l,1 ,I-trifluoroethyl radicals has been measured by applying the rotating sector technique to the gas phase photochlorination of 2,2-dichloro-l,l,l-trifluoroethane at 315°K. The observed value is 6.89 X 10' 2 cc/rnole .set. This value is in excel

Rotating sector study of the gas phase p
Rotating sector study of the gas phase photolysis of the carbon tetrachloride–cyclohexane system
✍ Merle L. White; Robert R. Kuntz 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 449 KB

## Abstract The rate constant for the combination of trichloromethyl radicals in the gas phase has been measured by applying the rotating sector technique to the gas phase carbon tetrachloride–cyclohexane photochemical system. A temperature‐independent rate constant, __k__~5~, of 3.9 ± 1.0 × 10^12^

The kinetic and mechanism of the gas pha
The kinetic and mechanism of the gas phase pyrolysis of 1,1,1,2-tetrachloropropane
✍ Rosa M. Domínguez; Gabriel Chuchani 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 331 KB

The gas phase pyrolysis of 1,1,1,2-tetrachloropropane was studied in a ,static system and seasoned vessel over the temperature range of 393.0-452.8"C and pressure range of 27.5-1 18.5 torr. The reaction is homogeneous, unimolecular, follows a first-order rate law, and is not affected by the presence

Kinetics of the thermal gas phase reacti
Kinetics of the thermal gas phase reactions of 1,2-epoxy-2-methylpropane
✍ M. C. Flowers; R. M. Parker 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB

The kinetics of the gas phase decomposition of 1,2-epoxy-2-methylpropane has been studied over the temperature range 377"-436°C at pressures between 5.3 and 61.6 torr. Isomerization reactions to give isobutyraldehyde, isopropenyl methyl ether, and P-methylprop-2-en-1-01 account for over 95% of the e