3-Chloro-2,2-dimethyIpropan-l-ol was pyrolysed in a static system at 410.0-459-1 "C and 62-179 Torr. The reaction, in a seasoned vessel and in the presence of the free radical suppressor propene, is homogeneous, unimolecular, and follows a first-order rate law. The rate coefficient follows the Arrhe
Existence of 1,2,3-Benzoxadiazole in the Gas Phase
β Scribed by Reinhard Schulz; Prof. Dr. Armin Schweig
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 204 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Ab initio quantum-chemical investigations are used to a bridged structure. The phenyl ion affinity toward P 2 has been determined and suggests that the phenyldiphos-outline the main differences between the phenyldiazonium cation [PhN 2 ] + (1a,b) and its P analogue [PhP 2 ] + (2a,b). Our phonium cat
The gas-phase pyrolysis kinetics of primary, secondary and tertiary 2-phenoxycarboxylic acids were studied over the temperature range 240.1-409.9 Β°C and pressure range 16.3-67.8 Torr. The elimination reactions, carried out in seasoned vessels and in the presence of the free radical chain inhibitor c
Nucleobase-derived radicals are crucial transient intermediates in the radiation damage of nucleic acids (RNA and DNA). Among the recognized mechanisms of radiation damage, capture of a low-energy electron followed by protonation of the transient anion radical results in the formation of hydrogen-at