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Theoretical Comparison of the Electronic Structures of [PhN2]+ and [PhP2]+ – Can the Benzenediphosphonium Cation Exist in the Gas Phase?

✍ Scribed by Geneviève Pfister-Guillouzo; Anna Chrostowska; Jean-Marc Sotiropoulos; Vadim D. Romanenko

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
269 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis

Ab initio quantum-chemical investigations are used to a bridged structure. The phenyl ion affinity toward P 2 has been determined and suggests that the phenyldiphos-outline the main differences between the phenyldiazonium cation [PhN 2 ] + (1a,b) and its P analogue [PhP 2 ] + (2a,b). Our phonium cation should be stable in the gas phase and that it is probably accessible by reaction between P 2 and Ph + . results show that in contrast to 1, 2b exists preferentially as

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