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Rotating sector study of the gas phase photolysis of the carbon tetrachloride–cyclohexane system

✍ Scribed by Merle L. White; Robert R. Kuntz

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
449 KB
Volume
3
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The rate constant for the combination of trichloromethyl radicals in the gas phase has been measured by applying the rotating sector technique to the gas phase carbon tetrachloride–cyclohexane photochemical system. A temperature‐independent rate constant, k~5~, of 3.9 ± 1.0 × 10^12^ cc mole^−1^ sec^−1^ was found. Arrhenius parameters for the reaction
were found to be given by the expression log k~4~ = 11.79 – (10,700/2.3 RT).

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