The Gas-Phase Structure of 1-Trifluoromethylthio-1,2,2-trifluoroethene, CF3SC(F)=CF2
โ Scribed by Olleta, Adriana ;Haas, Alois ;Oberhammer, Heinz
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1995
- Tongue
- English
- Weight
- 307 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0009-2940
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๐ SIMILAR VOLUMES
## Abstract The rate constants __k__~1~ for the reaction of CF~3~CF~2~CF~2~CF~2~CF~2~CHF~2~ with OH radicals were determined by using both absolute and relative rate methods. The absolute rate constants were measured at 250โ430 K using the flash photolysisโlaserโinduced fluorescence (FPโLIF) techni
Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 ฯฎ 2 K, have been measured as 0.034 ฯฎ 0.009 for the collision between CF 3 CH 2 CF 2 ฯฉ CF 3 radicals and as 0.075 ฯฎ 0.019 for CF 3 CH 2 CF 2 ฯฉ CF 3 CH 2 CF 2 radicals. The effect of the two fluori
The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products
## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical