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The Gas-Phase Structure of 1-Trifluoromethylthio-1,2,2-trifluoroethene, CF3SC(F)=CF2

โœ Scribed by Olleta, Adriana ;Haas, Alois ;Oberhammer, Heinz


Publisher
Wiley (John Wiley & Sons)
Year
1995
Tongue
English
Weight
307 KB
Volume
128
Category
Article
ISSN
0009-2940

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๐Ÿ“œ SIMILAR VOLUMES


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## Abstract The rate constants __k__~1~ for the reaction of CF~3~CF~2~CF~2~CF~2~CF~2~CHF~2~ with OH radicals were determined by using both absolute and relative rate methods. The absolute rate constants were measured at 250โ€“430 K using the flash photolysisโ€“laserโ€induced fluorescence (FPโ€LIF) techni

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Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 ฯฎ 2 K, have been measured as 0.034 ฯฎ 0.009 for the collision between CF 3 CH 2 CF 2 ฯฉ CF 3 radicals and as 0.075 ฯฎ 0.019 for CF 3 CH 2 CF 2 ฯฉ CF 3 CH 2 CF 2 radicals. The effect of the two fluori

The kinetics and the mechanism of the th
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The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products

Kinetics for the gas-phase reactions of
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## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical