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The Gas-Phase Structure of Trifluoromethyl Vinyl Sulfide, CF3SC(H)CH2

✍ Scribed by Lieb, Max ;Oberhammer, Heinz

Publisher
Wiley (John Wiley & Sons)
Year
1997
Tongue
English
Weight
292 KB
Volume
130
Category
Article
ISSN
0009-2940

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📜 SIMILAR VOLUMES

Substituent effects on the disproportion
Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. IV. Reactions of ·CF3 + CF3CH2CF2· and CF3CH2CF2· + CF3CH2CF2·
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Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 Ϯ 2 K, have been measured as 0.034 Ϯ 0.009 for the collision between CF 3 CH 2 CF 2 ϩ CF 3 radicals and as 0.075 Ϯ 0.019 for CF 3 CH 2 CF 2 ϩ CF 3 CH 2 CF 2 radicals. The effect of the two fluori

Substituent effects on the disproportion
Substituent effects on the disproportionation-combination rate constant ratios for gas-phase halocarbon radicals. Part III: Reactions of CF3 + CF3CH2 CHCF3 and CF3 CH2CHCF3 + CF3CH2 CHCF3
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Disproportionationkombination rate constant ratios, kd/&[, for the reactive collision between CF3CH2CHX + CF, radicals and between CF3CH2CHX + CF3CH2CHX radicals have been measured for X = CF, The kd/k, = 0.066 -t 0 01 3 when H is transferred to the CF3 radical and 0 I25 ? 0.025 for H transfer to th

Substituent effects on the disproportion
Substituent effects on the disproportionation—combination rate constant ratios for gas-phase halocarbon radicals, Part 5: Reactions of CF3 + CF3CH2CHCH3 and CF3CH2CHCH3 + CF3CH2CHCH3
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## Abstract Rate constant ratios, __k__~d~/__k__~c~ for the disproportionation/combination reaction have been measured as 0.07 ± 0.02 when an H is removed from the CH~2~ position of the CF~3~CH~2~CHCH~3~ radical and as 0.24 ± 0.03 when the H is removed from the CH~3~ position in the reaction with t

Structure of ions [ZnNCR]+ and [Zn(NCR)2
Structure of ions [ZnNCR]+ and [Zn(NCR)2]+ (R = H, CH3) in the gas phase
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## Abstract Structures of [ZnNCR]^+^ and [Zn(NCR)~2~]^+^ ions (R = H, Me), which are abundant in the mass spectra of many types of coordination compounds, were studied by the MNDO method. In all cases the most stable isomers correspond to the zinc ion coordinated with the nitrogen(s) of the nitrile