✦ LIBER ✦

Structure of ions [ZnNCR]+ and [Zn(NCR)2]+ (R = H, CH3) in the gas phase

✍ Scribed by Sergiu P. Palii; Nikolai I. Raevskii; Dmitrii V. Zagorevskii; Konstantin M. Indrichan; Yurii A. Borisov; Nikolai V. Gerbeleu; Yurii S. Nekrasov; D. V. Zagorevskii; Yu. S. Nekrasov; O- S. Timofeev; A. I. Gren'

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 235 KB
Volume: 26
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210260905

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Structures of [ZnNCR]^+^ and [Zn(NCR)~2~]^+^ ions (R = H, Me), which are abundant in the mass spectra of many types of coordination compounds, were studied by the MNDO method. In all cases the most stable isomers correspond to the zinc ion coordinated with the nitrogen(s) of the nitrile ligand. For [Zn(NCR)~2~]^+^, the N‐Zn‐N angles are ∼108°.

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