Room-Temperature ortho -Alkoxylation and -Halogenation of N -Tosylbenzamides by Using Palladium(II)-Catalyzed CH Activation
✍ Scribed by Péron, Florent; Fossey, Christine; Sopkova-de Oliveira Santos, Jana; Cailly, Thomas; Fabis, Frédéric
- Book ID
- 121823637
- Publisher
- John Wiley and Sons
- Year
- 2014
- Tongue
- English
- Weight
- 609 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0947-6539
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## Abstract **Pd and CO—ureally got me!** The title reaction proceeds efficiently at 18 °C under CO (1 atm) with 5 % [Pd(OTs)~2~(MeCN)~2~] as precatalyst. Depending on the solvents used, either anthranilates or cyclic imides can be obtained in high yields (see picture, BQ=benzoquinone, Ts=4‐toluene