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ChemInform Abstract: Room-Temperature Palladium-Catalyzed C—H Activation: ortho-Carbonylation of Aniline Derivatives.

✍ Scribed by Chris E. Houlden; Marc Hutchby; Chris D. Bailey; Gair Ford; Simon N. G. Tyler; Michel R. Gagne; Guy C. Lloyd-Jones; Kevin I. Booker-Milburn

Publisher
John Wiley and Sons
Year
2009
Weight
54 KB
Volume
40
Category
Article
ISSN
0931-7597

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Abstract

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Room-Temperature Palladium-Catalyzed CH
Room-Temperature Palladium-Catalyzed CH Activation: ortho-Carbonylation of Aniline Derivatives
✍ Chris E. Houlden; Marc Hutchby; Chris D. Bailey; J. Gair Ford; Simon N. G. Tyler 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB 👁 1 views

## Abstract **Pd and CO—ureally got me!** The title reaction proceeds efficiently at 18 °C under CO (1 atm) with 5 % [Pd(OTs)~2~(MeCN)~2~] as precatalyst. Depending on the solvents used, either anthranilates or cyclic imides can be obtained in high yields (see picture, BQ=benzoquinone, Ts=4‐toluene