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Room-Temperature Palladium-Catalyzed CH Activation: ortho-Carbonylation of Aniline Derivatives

✍ Scribed by Chris E. Houlden; Marc Hutchby; Chris D. Bailey; J. Gair Ford; Simon N. G. Tyler; Michel R. Gagné; Guy C. Lloyd-Jones; Kevin I. Booker-Milburn

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
314 KB
Volume
48
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

Pd and CO—ureally got me! The title reaction proceeds efficiently at 18 °C under CO (1 atm) with 5 % [Pd(OTs)~2~(MeCN)~2~] as precatalyst. Depending on the solvents used, either anthranilates or cyclic imides can be obtained in high yields (see picture, BQ=benzoquinone, Ts=4‐toluenesulfonyl).magnified image

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ChemInform Abstract: Room-Temperature Pa
ChemInform Abstract: Room-Temperature Palladium-Catalyzed C—H Activation: ortho-Carbonylation of Aniline Derivatives.
✍ Chris E. Houlden; Marc Hutchby; Chris D. Bailey; Gair Ford; Simon N. G. Tyler; M 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 54 KB 👁 1 views

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