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Palladium-Catalyzed Carbonylative CH Activation of Heteroarenes

✍ Scribed by Xiao-Feng Wu; Dr. Pazhamalai Anbarasan; Dr. Helfried Neumann; Prof. Dr. Matthias Beller

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
320 KB
Volume
49
Category
Article
ISSN
0044-8249

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✍ Chris E. Houlden; Marc Hutchby; Chris D. Bailey; J. Gair Ford; Simon N. G. Tyler 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB 👁 1 views

## Abstract **Pd and CO—ureally got me!** The title reaction proceeds efficiently at 18 °C under CO (1 atm) with 5 % [Pd(OTs)~2~(MeCN)~2~] as precatalyst. Depending on the solvents used, either anthranilates or cyclic imides can be obtained in high yields (see picture, BQ=benzoquinone, Ts=4‐toluene