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Role of spin-rotation relaxation in solid CH4-Kr mixtures

✍ Scribed by F. de Luca; B. Maraviglia; L. Morici; C. Nuccetelli


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
253 KB
Volume
122
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


Octupolar glass structure in a solid Ch4
✍ F. De Luca; B. Maraviglia πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 244 KB

Evidence for the existence of an orientational glass structure in a CH4---Kr mixture with 35% Rr was obtained with MlR measurements. Our results sdd an "octupolar ghss" to the already known "quadrupolar glass" of ortho-para hydrogen.

Spin-rotational relaxation for protons i
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Proton spin-&t&u refasation times rvere measured in soIid NI-I.+CIOq from 80 to 400Β°K. Relow 200Β°K the observed relsstltion times are due to dipoh interaction, abox that iemp--rature spin-rotational interactions become predominani. A potential barrier of 0.70 kcal mole-' was obtained for the reorie

Spin diffusion and spin-lattice relaxati
✍ M. Alla; R. Eckman; A. Pines πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 408 KB

SelectIre NhlR TI mrasurements on dcutermm m pouders rotatrng at high speed at the magtc angle mdtcate that dlpolat spm dlffusmn ~~hich can bc quenched by the ortentattonal dependence of the quadrupole spbttmg, IS partially restored by the simple rotatton

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✍ L.J. Burnett; B.H. Muller πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 English βš– 402 KB

Non-exponential proton spin-lattice relasation has been observed in solid Cl-I&H3 and CHsCD;. Comparison with recent theoretic31 predictions indicates XI intermethyl cross-correlation effect in CH&HJ which operates inaddition to the more commonly observed intramethyl cross-correlation intelactions.