Role of (NO) 2 Dimer in Reactions of Fe + with NO and NO 2 Studied by ICP-SIFT Mass Spectrometry
โ Scribed by Blagojevic, Voislav; Jarvis, Michael J. Y.; Koyanagi, Gregory K.; Bohme, Diethard K.
- Book ID
- 127347126
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 997 KB
- Volume
- 117
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
## Abstract A novel technique is described for forming groundโstate SO __X__^3^ฮฃ^๏ฃฟ^ radicals free of reactive impurities in a dischargeโflow system. Mass spectrometric detection of SO and ClO free radicals has been used to study the kinetics of the following reactions at 295 K: equation image
The rate constants for reactions (4) and (5) ( 4 ) CFCI,O, 7 NO -+CFCI,O + NO, ( 5 ) CFCI,O, + NO, + M -CFCI,O,NO, -M were determined at room temperature by pulsed laser photolysis and time resolved mass spectrometry. A description of the experimental setup is given. CFCI,O, radicals were generated