Reactions of Methyl- and Ethylperoxy Radicals with NO Studied by Time-Resolved Negative Ionization Mass Spectrometry
β Scribed by Xing, Jia-Hua; Nagai, Yoko; Kusuhara, Masayuki; Miyoshi, Akira
- Book ID
- 126154350
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 157 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The rate constants for reactions (4) and (5) ( 4 ) CFCI,O, 7 NO -+CFCI,O + NO, ( 5 ) CFCI,O, + NO, + M -CFCI,O,NO, -M were determined at room temperature by pulsed laser photolysis and time resolved mass spectrometry. A description of the experimental setup is given. CFCI,O, radicals were generated
## Abstract A novel technique is described for forming groundβstate SO __X__^3^Ξ£^ο£Ώ^ radicals free of reactive impurities in a dischargeβflow system. Mass spectrometric detection of SO and ClO free radicals has been used to study the kinetics of the following reactions at 295 K: equation image