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Ring Currents as Probes of the Aromaticity of Inorganic Monocycles : P5−, As5−, S2N2, S3N3−, S4N3+, S4N42+, S5N5+, S42+ and Se42+

✍ Scribed by Frank De Proft; Patrick W. Fowler; Remco W. A. Havenith; Paul von Ragué Schleyer; Gregory Van Lier; Paul Geerlings


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
677 KB
Volume
10
Category
Article
ISSN
0947-6539

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Two new 1,2,3,5-dithiadiazoles, [4-(4Ј-C 5 H 4 N)CN 2 S 2 ] (L 1 ) and [4-(3Ј-C 5 H 4 N)CN 2 S 2 ] (L 2 ), with different pyridyl groups at the 4-position were prepared. As Lewis bases, the dithiadiazoles reacted with Lewis acids via their pyridyl groups to form acid-base adducts with retention of t