Synthesis and Crystal Structures of the
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D. V. Griffiths; S. J. Parrott; M. Togrou; J. R. Dilworth; Yifan Zheng; S. Ritte
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Article
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1998
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John Wiley and Sons
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German
⚖ 141 KB
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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure