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Reactions of S4N4 with phosphineiridium(I) complexes. Synthesis and crystal structures of [(dppen)2Ir(S2N2)](BPh4) · 0.5CH3COCH3 and (dppen)2Ir(S2N2)[W(CO)5](BPh4) · 0.5CH2Cl2

✍ Scribed by Carlo A. Ghilardi; Stefano Midollini; Simonetta Moneti; Annabella Orglandini


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
881 KB
Volume
312
Category
Article
ISSN
0022-328X

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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure