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ChemInform Abstract: Enantioselective Hydrogenation in the Presence of the Rhodium(I) Complex with (+)-4S,5S-N4,N4,N5,N 5,2,2-Hexamethyl-1,3-dioxolane-4,5-dimethaneamine.

✍ Scribed by L. O. Nindakova; B. A. Shainyan; A. I. Albanov

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200231028

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The reactions of [N 3 P 3 (dobp) 2 Cl 2 ] and [N 3 P 3 (dobp)Cl 4 ] with revealed that the complexation of the N atom of one 4oxypyridine ligand by the W(CO) 5 fragment has a a mixture of HOC 5 H 4 N-4 and K 2 CO 3 in acetone give the cyclotriphosphazenes [N 3 P 3 (dobp) 2 (OC 5 H 4 N-4) 2 ] and [N