✦ LIBER ✦

Review of Rate Constants and Exploration of Correlations of the Halogen Transfer Reaction of Trisubstituted Carbon-Centered Radicals with Molecular Halogens

✍ Scribed by Poutsma, Marvin L.

Book ID: 111654724
Publisher: American Chemical Society
Year: 2012
Tongue: English
Weight: 766 KB
Volume: 77
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo2023075

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Rate constants for the gas–phase reactio

Rate constants for the gas–phase reactions of OH radicals with ethylene and halogenated ethylene compounds

✍ Howard, Carleton J. 📂 Article 📅 1976 🏛 American Institute of Physics 🌐 English ⚖ 769 KB

Silicon radicals. Relative rates and sel

Silicon radicals. Relative rates and selectivity ratios in the radical reactions of silicon-hydrogen bonds with carbon-halogen bonds

✍ Sommer, Leo H.; Ulland, L. Arlie 📂 Article 📅 1972 🏛 American Chemical Society 🌐 English ⚖ 539 KB

Rate constants of reactions of chlorine

Rate constants of reactions of chlorine atoms with aliphatic hydrocarbons and halogen derivatives in the liquid phase

✍ G. B. Sergeev; V. V. Smirnov; E. V. Porodenko; A. V. Pukhovsky 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 511 KB

The kinetics of liquid phase chlorination of methane in a difluorodichloromethane medium has been studied in a temperature interval of 293-150 K. The value of activation energy found for the hydrogen abstraction stage by a chlorine atom (El) equals 14.2 \* 2.5 kJ/mol, with the processes of chlorine

Rate constants and Arrhenius parameters

Rate constants and Arrhenius parameters for the reactions of some carbon-centered radicals with tris(trimethylsilyl)silane

✍ Chatgilialoglu, C.; Dickhaut, J.; Giese, B. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 615 KB

Rate constants for the combination of tr

Rate constants for the combination of trichloromethyl radicals and the electron-transfer reaction between hydroxymethyl radicals and carbon tetrachloride in solution

✍ H. Paul 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 728 KB

## Abstract The rate constant for the bimolecular combination of trichloromethyl radicals in methanol is determined as a function of temperature by steady‐state kinetics and electron‐spin resonance with modulated radical initiation. The rate constant is in accord with the Smoluchowski equation and

Rate constants for the reactions of HCCC

Rate constants for the reactions of HCCCO and NCCO radicals with molecular oxygen

✍ Takashi Imamura; Nobuaki Washida 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 349 KB

Reactions of HCCCO and NCCO radicals with O 2 have been studied by a combination of pulsed laser photolysis and photoionization mass spectrometry. HCCCO was produced by 193-nm photolysis of methylpropiolate or 3-butyn-2-one, and NCCO was formed by 193-nm photolysis of acetylcyanide. The rate constan