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Rate constants and Arrhenius parameters for the reactions of some carbon-centered radicals with tris(trimethylsilyl)silane

✍ Scribed by Chatgilialoglu, C.; Dickhaut, J.; Giese, B.

Book ID
127286332
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
615 KB
Volume
56
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

The Tris(trimethylsilyl)silane/Thiol Red
The Tris(trimethylsilyl)silane/Thiol Reducing System: A Tool for Measuring Rate Constants for Reactions of Carbon-Centered Radicals with Thiols
✍ Chryssostomos Chatgilialoglu πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 125 KB

## Abstract An extension of the well‐known β€˜free‐radical‐clock’ methodology is described that allows one to determine the rate constants of carbon‐centered radicals with a variety of thiols by using the tris(trimethylsilyl)silane/thiol couple as a reducing system. A total of 20 rate constants for t