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Reversible retro-Diels-Alder reactions of bicyclo[4.1.0]hept-2-ene systems

✍ Scribed by Sellers, Simon F.; Dolbier, William R.; Koroniak, Henryk; Al-Fekri, Dheya M.


Book ID
126792691
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
529 KB
Volume
49
Category
Article
ISSN
0022-3263

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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond