## Abstract The three title monomers were polymerized using a variety of Ru‐, Ir‐, Mo‐, W‐ and Re‐based metathesis catalyst systems to yield polymers having a wide range of __cis__ double bond contents in each case. The ^13^C NMR spectra of the polymers were interpreted in terms of __cis/trans__, h
✦ LIBER ✦
Stereochemistry of the Thermal Retro-Diels−Alder Reactions of cis , exo - 5 , 6 - d 2 -Bicyclo[2.2.1]hept-2-ene, cis - 4 , 5 - d 2 -Cyclohexene, and cis , exo - 5 , 6 - d 2 -Bicyclo[2.2.2]oct-2-ene
✍ Scribed by Lewis, David K.; Glenar, David A.; Hughes, Steven; Kalra, Bansi L.; Schlier, Jessica; Shukla, Rajesh; Baldwin, John E.
- Book ID
- 125898047
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 34 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The face selectivity (__endo__‐face __vs. exo__‐face attack onto the exocyclic s‐__cis__‐butadiene moiety) of the [4+2]cycloadditions of 5,6‐bis((D)methylidene)‐2‐bicyclo‐[2.2.2]octene (**11**) to strong dienophiles has been determined in benzene at 25°. It is __ca.__ 95/5, 75/5, 70/30,