𝔖 Bobbio Scriptorium

✦ LIBER ✦

Thermal rearrangement of 5,6-benzotricyclo[3.2.0.02,7]hept-5-ene into 2-vinylindene via an intramolecular retro-Diels-Alder reaction

✍ Scribed by Adam, Waldemar; De Lucchi, Ottorino

Book ID: 126844991
Publisher: American Chemical Society
Year: 1980
Tongue: English
Weight: 252 KB
Volume: 45
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01309a020

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Qhiral pathways in the thermal rearrange

Qhiral pathways in the thermal rearrangement of 3,7-dimethylene-1-ethyltricyclo[4.1.02,4]heptane to 2,5-dimethylene-3-ethylbicyclo[4.1.0]hept-3-ene. Decyclization of a pair of 2,2'-linked methylenecyclopropanes avoids a symmetrical 2,5-dimethylenecyclohept-3-ene-1,6-diyl biradical intermediate

✍ Wendt, Michael D.; Berson, Jerome A. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 297 KB

Chiral pathways in the thermal rearrange

Chiral pathways in the thermal rearrangement of 3,7-dimethylene-1-ethyltricyclo[4.1.0.02,4]heptane to 2,5-dimethylene-3-ethylbicyclo[4.1.0]hept-3-ene. Decyclization of a pair of 2,2'-linked methylenecyclopropanes avoids a symmetrical 2,5-dimethylenecyclohept-3-ene-1,6-diyl biradical intermediate [Erratum to document cited in CA115(1):7868r]

✍ Wendt, Michael D.; Berson, Jerome A. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 135 KB