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Reversible nethide shifts in the 2-tert-butyl-2-adamantyl cation

✍ Scribed by James L. Fry; James A. Saba

Book ID
104220234
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
178 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of either 2-tert-butyl-2-adamantanol or 2-lsopropenyl-2-methyladamantane with acid in the presence of a reducing agent (hydrogen iodide or tn-c-hexylsllane) yielded 2-tert-butyladamantane as the maJor or exclusive product buw2-adamantyl cation at -78Β°C in FS03H-SbF5-S02ClF

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