Isomeric Alkyl Cation/Arene Complexes in
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Antonello Filippi; Graziella Roselli; Gabriele Renzi; Felice Grandinetti; Mauriz
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Article
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2003
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John Wiley and Sons
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English
β 155 KB
π 2 views
## Abstract The kinetics and the stereochemistry of the protonationβinduced unimolecular isomerization of (__S__)β(+)β1βD~1~β3β(__p__βtolyl)butane have been investigated in the gas phase in the 100β160βΒ°C range. The process leads to the almost exclusive formation of the relevant __meta__ isomer wit