Treatment of either 2-tert-butyl-2-adamantanol or 2-lsopropenyl-2-methyladamantane with acid in the presence of a reducing agent (hydrogen iodide or tn-c-hexylsllane) yielded 2-tert-butyladamantane as the maJor or exclusive product buw2-adamantyl cation at -78°C in FS03H-SbF5-S02ClF
Carbocationic rearrangements originating from the 2-tert-butyl-2-adamantyl system
✍ Scribed by Saba, James A.; Fry, James L.
- Book ID
- 126316752
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 580 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
The hetero-Cope rearrangement of 4-tert-butyl-phenyl-tert-butylhydroxylamine provides an easy access to the corresponding ortho-bromoaniline, converted to the new highly water-soluble nitroxide, potassium 5-tert-butyl-2-(tert-butyl-aminoxy)benzoate. The parent carboxylic acid was found to be very pe
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