𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Exceptionally high barriers to 1,2-hydride shifts in the 1-adamantyl cation

✍ Scribed by Pierre Vogel; Martin Saunders; Wilfried Thielecke; Paul von Ragué Schleyer


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
119 KB
Volume
12
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Vinyl cations, 22 a 1,2-hydride shift in
✍ Klaus-Peter Jäckel; Michael Hanack 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 137 KB

Recently we reprted about the first example of a 1.2-hydride shift durmg the generation of a vrnyl cation, a process well known for trlsubstituted car&mum ions 2) :Thls was obsermildurlng the solvolys~s of cls-and trans-3-cyclop~l-2-propen-2-yl-trifl~~~esulfo~~(tnflate)3! --The 1.2-hydride shLft was

Competitive 1,2- and 1,3-hydride shifts
✍ Harry R. Hudson; Andrew J. Koplick; David J. Poulton 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 186 KB

Many examples of rearrangement which occur in straight-chain alkyl groups during kinetically controlled substitutions can be formally represented as proceeding via successive 1,2-shifts in intermediate carbonium ions.' -In certain cases, this mechanism has been