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Competitive 1,2- and 1,3-hydride shifts in the thermal decomposition of N-alkyl chloroformates

✍ Scribed by Harry R. Hudson; Andrew J. Koplick; David J. Poulton

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 186 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72166-6

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✦ Synopsis

Many examples of rearrangement which occur in straight-chain alkyl groups during kinetically controlled substitutions can be formally represented as proceeding via successive 1,2-shifts in intermediate carbonium ions.' -In certain cases, this mechanism has been

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