## Abstract The Debije‐Scherrer diagram of “natural” L(+)‐muscarine‐di‐__p__‐toluyl‐hydrogen‐D(−)‐tartrate‐hemihydrate is compared with the diagrams of muscarine‐di‐__p__‐toluyl‐hydrogen‐D(−)‐tartrates resulting from the resolution of two DL‐muscarine preparations. One of the latter diagrams proved
Resolution von DL-p-Bromphenylalanin
✍ Scribed by R. Schwyzer; E. Surbeck-Wegmann
- Publisher
- John Wiley and Sons
- Year
- 1960
- Tongue
- German
- Weight
- 252 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The resolution of DL‐p‐bromophenylalanine into the D‐ and L‐antipodes via the ester salts with dibenzyol D‐ and L‐tartaric acids is described.
📜 SIMILAR VOLUMES
Isovaline (I) is of considerable interest cosmologically in that (1) it is one of the twelve non-protein amino acids which have been isolated from the Murchison meteorite\* and (2) unlike the other chiral amino acids in this meteorite, it has no ahydrogen at its asymmetric center and hence cannot ra
## Abstract Die Synthese von dl‐Desoxynupharidin (I), eines 1.7‐Dimethyl‐4‐[furyl‐(3)]‐chinolizidins, aus 2.5‐Lutidin wird beschrieben. Das IR‐Spektrum des synthetischen Desoxynupharidins ist praktisch mit dem des natürlichen Alkaloids aus __Nuphar japonicum__ identisch.
## Abstract DL‐Dihomo‐tryptophan (VII) erhält man aus Homotryptophol (IIa) entweder durch Umsetzung des daraus gebildeten Homotryptophylbromids (III) oder von Homotryptophyltosylat (II b) mit Natrium‐acetaminomalonsäure‐dimethylester und Hydrolyse des Alkylierungsprodukts. — Zur Darstellung von DL‐
[14C] DL-phenylalanine and [35S]DL-methionine were resolved using cellulose column chromatography. The assignment for the resolved enantiomers was carried out by means of co-chromatography with non-labeled oL-amino acids after modification with fluorodinitrobenzene. The optical purity of the enanti