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Relative yields of electronically excited iodine atoms, I(5 2P12), in the photolysis of alkyl iodides

✍ Scribed by T. Donohue; J.R. Wiesenfeld

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 509 KB
Volume: 33
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85480-7

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✦ Synopsis

The fraction of electronically excited iodine atoms, I(5 2P,/&, formed in the broadband flash photolysis of several alkyl iodides has been determined using time-resolved static absorption spectroscopy. By monitoring the temporal proftie of the ground state, I(5 *Pa/z), following the photolytic pulse, the initial yields of ground and electronically excited atoms may be obtained. Deactivation rates of I(5 *PI/~) by these alkyl iodides are also reported.

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