The gas-phase electron paramagnetic resonance spectrum of excited (4p5 2P12) bromine atoms
β Scribed by P.B. Davies; B.A. Thrush; A.J. Stone; F.D. Wayne
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 259 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0009-2614
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A method is described for the phot~le~c me~~ment of the time-resolved atomic absorption by electronically excited iodine atoms, 1(5'Prn), generated by pulsed irradiation-A kinetic investigation of the decay of these excited atoms yields a vaIlle for the quenching rate constant by mo?ecuku oxygen, th
The fraction of electronically excited iodine atoms, I(5 2P,/&, formed in the broadband flash photolysis of several alkyl iodides has been determined using time-resolved static absorption spectroscopy. By monitoring the temporal proftie of the ground state, I(5 \*Pa/z), following the photolytic puls
Electron resonance gas phase transitions with a polarization paraUe1 to the externa! maSrwtic fietd are reported \* in halogen atoms Atoms are produced inside the ESR cavity by means of a hot-wire method. 1. Introduction Electron resonance spectra of chlorine f l] , bromine [Z] and iodine [31 atoms