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Regioselectivity on the Palladium-Catalyzed Intramolecular Cyclization of Indole Derivatives

โœ Scribed by Abbiati, Giorgio; Beccalli, Egle M.; Broggini, Gianluigi; Zoni, Caterina

Book ID
121490254
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
72 KB
Volume
68
Category
Article
ISSN
0022-3263

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Uncommon intramolecular palladium-cataly
Uncommon intramolecular palladium-catalyzed cyclization of indole derivatives
โœ Egle M. Beccalli; Gianluigi Broggini ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 73 KB

A novel synthetic strategy based on the intramolecular palladium-catalyzed oxidative cyclization reaction, allows the formation of C-C bond and the synthesis of b-carbolinones. The reaction has been performed in the presence of catalytic amount of PdCl 2 (CH 3 CN) 2 and benzoquinone as a reoxidant.