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Regioselectivity on the Palladium-Catalyzed Intramolecular Cyclization of Indole Derivatives.

✍ Scribed by Giorgio Abbiati; Egle M. Beccalli; Gianluigi Broggini; Caterina Zoni

Publisher
John Wiley and Sons
Year
2004
Weight
88 KB
Volume
35
Category
Article
ISSN
0931-7597

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Remote Substituent Effects on the Enantiomeric Excess of Intramolecular Asymmetric Palladium-Catalyzed Polyene Cyclizations. -Remote substituents show a strong influence on the enantioselectivity of the title reactions. Excellent enantioselectivity is obtained by cyclization of the O-methyl triflate