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Palladium-catalyzed intramolecular cyclization of vinyloxirane regioselective formation of cyclobutanol derivative

โœ Scribed by Martine Zucco; Franck Le Bideau; Max Malacria


Book ID
103404922
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
178 KB
Volume
36
Category
Article
ISSN
0040-4039

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โœ Egle M. Beccalli; Gianluigi Broggini ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 73 KB

A novel synthetic strategy based on the intramolecular palladium-catalyzed oxidative cyclization reaction, allows the formation of C-C bond and the synthesis of b-carbolinones. The reaction has been performed in the presence of catalytic amount of PdCl 2 (CH 3 CN) 2 and benzoquinone as a reoxidant.