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Regioselective synthesis of trifluoromethyl group containing allylic amines by palladium-catalyzed allylic amination and sequential isomerization

โœ Scribed by Takuya Hirakawa; Kazunori Ikeda; Daiji Ikeda; Tomoko Tanaka; Hiroshi Ogasa; Motoi Kawatsura; Toshiyuki Itoh


Book ID
113928910
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
663 KB
Volume
67
Category
Article
ISSN
0040-4020

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Palladium(O) catalyzed azidation and ami
โœ Shun-Ichi Murahashi; Yoshio Tanigawa; Yasushi Imada; Yuki Taniguchi ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 240 KB

Palladium catalyzed reaction of ally1 acetates with azide ion gives ally1 azides, which are readily converted into the corresponding primary allylamines upon treatment with PPhS/NaOH. The catalytic transformation of allylic substrates via n-ally1 palladium complexes is now well d0cumented.l