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Palladium(O) catalyzed azidation and amination of allyl acetates. Selective synthesis of allyl azides and primary allylamines

✍ Scribed by Shun-Ichi Murahashi; Yoshio Tanigawa; Yasushi Imada; Yuki Taniguchi

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
240 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

Palladium catalyzed reaction of ally1 acetates with azide ion gives ally1 azides, which are readily converted into the corresponding primary allylamines upon treatment with PPhS/NaOH. The catalytic transformation of allylic substrates via n-ally1 palladium complexes is now well d0cumented.l

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