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Regio- and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C 5 Me 5 ) 2 Sm(thf) n

โœ Scribed by Takaki, Ken; Kusudo, Takeshi; Uebori, Shinya; Nishiyama, Tetsushi; Kamata, Tohru; Yokoyama, Masaki; Takehira, Katsuomi; Makioka, Yoshikazu; Fujiwara, Yuzo


Book ID
126816430
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
91 KB
Volume
63
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Regio- and Stereoch
โœ K. TAKAKI; T. KUSUDO; S. UEBORI; T. NISHIYAMA; T. KAMATA; M. YOKOYAMA; K. TAKEHI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 41 KB ๐Ÿ‘ 2 views

Regio-and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C 5 Me 5 ) 2 Sm(thf )n. -The reductive cleavage of the C-O bond of allylic benzyl ethers with Sm(C 5 Me 5 ) 2 (thf) 2 leads to substituted allylic Sm complex intermed