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A facile generation of organosamariumη3-allyl complexes by reductive cleavage of allylic ethers with (C5Me5)2Sm(THF)n

✍ Scribed by Ken Takaki; Takeshi Kusudo; Shinya Uebori; Yoshikazu Makioka; Yuki Taniguchi; Yuzo Fujiwara

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
192 KB
Volume
36
Category
Article
ISSN
0040-4039

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✍ K. TAKAKI; T. KUSUDO; S. UEBORI; T. NISHIYAMA; T. KAMATA; M. YOKOYAMA; K. TAKEHI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 41 KB 👁 2 views

Regio-and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C 5 Me 5 ) 2 Sm(thf )n. -The reductive cleavage of the C-O bond of allylic benzyl ethers with Sm(C 5 Me 5 ) 2 (thf) 2 leads to substituted allylic Sm complex intermed