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ChemInform Abstract: A Facile Generation of Organosamarium η3-Allyl Complexes by Reductive Cleavage of Allylic Ethers with (C5Me5)2Sm(THF)n.

✍ Scribed by K. TAKAKI; T. KUSUDO; S. UEBORI; Y. MAKIOKA; Y. TANIGUCHI; Y. FUJIWARA

Book ID
112023122
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Regio- and Stereoch
ChemInform Abstract: Regio- and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C5Me5)2Sm(thf)n.
✍ K. TAKAKI; T. KUSUDO; S. UEBORI; T. NISHIYAMA; T. KAMATA; M. YOKOYAMA; K. TAKEHI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 41 KB 👁 2 views

Regio-and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C 5 Me 5 ) 2 Sm(thf )n. -The reductive cleavage of the C-O bond of allylic benzyl ethers with Sm(C 5 Me 5 ) 2 (thf) 2 leads to substituted allylic Sm complex intermed